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Trey Fort led Mississippi State to victory with 21 points, 14 of which came in the first quarter.
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Mississippi State shot 40% from beyond the arc in the Barstool Sports Invitational in Chicago.
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The second half saw Arizona State making a late push, with most of their points coming in garbage time.
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Team captains Jamiya Neal and Frankie Collins combined for 15 points but struggled with their shooting.
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Kamari Lands led Arizona State with 13 points, while Jose Perez had a strong first half but didn't score in the second.
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Mississippi State moved to 1-0, looking like contenders in the SEC, while Arizona State fell to 0-1 in an embarrassing performance for Bobby Hurley's squad.
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